Theoretical Investigation on NiF2 /Picolinic Acid-Catalyzed Chemoselective Coupling−Cyclization of 2‑Iodobenzamide and Malonate to Furnish Homophthalimide
The first theoretical investigation on NiF2 /picolinic acid-catalyzed chemoselective cou-pling− cyclization of 2-iodobenzamide and malonate was provided by our DFT calculation. First in Ni(I)/ Ni(III) catalytic cycle, NiF2 and PicA are converted to L2 Ni(II) complex together with leaving of…...
10.5281/zenodo.22848045